Professor Leo Radom

  • radom@chem.usyd.edu.au
  • University of Sydney
  •  

    Position

    ARC Australian Professorial Fellow in the School of Chemistry, the University of Sydney.

    Qualifications
    •    Fellow, Senior Fellow, Professorial Fellow, Professor, (1974- 2003) ANU.
    •    QE II Fellow (1972-1974), Research School of Chemistry, ANU.
    •    Postdoctoral studies (1969-1972) Carnegie-Mellon University, USA with John Pople
    •    PhD (1969) the University of Sydney.
    •    Elected to the Australian Academy of Science (1988) and to the International Academy of Quantum Molecular Science (1988).
    •    President of the World Association of Theoretical and Computational Chemists (WATOC).

    Expertise
    •    Computational quantum chemistry.
    •    Theoretical studies of the chemistry of free radicals.

    Key Areas of Research

    •    Stabilities and reactions of free radicals, including peptide radicals.
    •    Oxidative damage to proteins, including particularly HOCl- and HOBr-mediated damage.
    •    Enzyme-catalyzed reactions, including B12-mediated radical mechanisms.
    •    Transition-metal-free hydrogenation and hydogenolysis, including comparisons of radical and ionic mechanisms, and hydrogen bonding.
    •    Alkali metal chemistry, including structures and other properties of small alkali-metal-containing radicals.
    •    Formulation and assessment of improved theoretical procedures, including improved
    •    methods for the description of radicals.

    Selected Publications

    Tian, Z; Chan, B; Sullivan, MB; Radom, L; Kass, SR. Proc. Nat. Acad. Sci. 2008, 105, 7647–7651.

    Sandala, GM; Smith, DM; Radom, L. J. Am. Chem. Soc. 2008, 130, 10684–10690.